Work backwards, step by step to derive the amount of water at the beginning.
3rd Stop    3rd Refill    2nd Stop     2nd Refill    1st Stop    1st Refill
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  500           250         750             375          875         437.5
- 500       + 250       - 500          + 375       - 500          437.5
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    0            500         250              750         375          875
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He had 437.5 ml water in the bottle at the beginning of the race.
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